Replacing ammonium hydroxide with a safer alternative provides the best employee protection. Ammonium hydroxide is a colorless liquid with a strong odor and bad taste. In addition to engineering controls, employers can use administrative controls to reduce employee exposure to a safe level. For safety management, use Hazcards and other resources on the CLEAPSS website. Avoid release to theenvironment. These can include work schedules that rotate employees and trainings. Identification . Some employers may choose to use stricter PELs provided by organizations like the National Institute for Occupational Safety and Health (NIOSH), which set an 8-hour TWA of 25 ppm. Ammonium Hydroxide, ACS Reagent . NIOSH also set a short-term suggested TWA of 35 ppm. nws4�8߷q\���L�I�u���-n���Z�{"��� Replacing ammonium hydroxide with a safer alternative provides the best employee protection. Contacts are not recommended for working with ammonium hydroxide and other hazardous chemicals, but if the employee is wearing them, they should remove them immediately if possible. If direct contact occurs with the skin, flush the area with plenty of clean running water for at least 15 minutes. In general, employers must provide PPE to employees at no cost. If breathing is difficult, give oxygen. *Please select more than one item to compare Product Name: Ammonium Hydroxide, ACS Reagent. endstream endobj startxref Soda lime. Compare Products: Select up to 4 products. MSDS MATERIAL SAFETY DATA SHEET CHEMTREC: 800-424-9300 (USA) ----- 703-527-3887(Outside USA and Canada) CANUTEC: 613-996-6666 … If other hazard controls are unable to reduce employee exposure to safe levels, they may be required to use PPE. Also known as caustic soda and caustic potash. Although the name ammonium hydroxide suggests an alkali with composition [NH 4 +][OH −], it is actually impossible to isolate samples of NH 4 OH. Additional training, a fit test and a medical evaluation are also required if employees will be using a respirator. Labels: Colleges & UniversitiesConstructionFood SafetyHospitality & Food ServiceInformational ArticlesLaboratory SafetyManufacturingMunicipalitiesOther/General IndustryRetail & Grocery, Each year, the Association of Workers’ Compensation Boards of Canada (AWCBC) reports on the number of fatal workplace injuries…, In the 1960s, more women than ever entered the American workforce, highlighting issues of gender equality and workplace sexual…, Safe Driving in Hazardous Weather The Federal Highway Administration estimates that more than 1.2 million weather-related accidents happen on…, SAFETYSKILLS 519 NW 23rd Street Suite 200 Oklahoma City, OK 73103 T. 405-463-6656 SUPPORT | CONTACT US. Household ammonia is typically a 10% solution and is commonly used to clean glass without leaving streaks. h��W_o�6�G�c��EJ�`�/�4��e��FQc��dH2�~�nw���n�ހm0���w�8��%���n�k@]�#R/r���p�q9�0.�� �*!�� "4sዃ3�$�F_Q���� �.L@N�ۈ�,߿gqk;6��~��������!���''�f�A�/�9���4iB8����NQ\������uՒ͛j�4W�J���l��o��EV|nc�EQ6''6 u`.�_��DB���J"��,�t�:}��E�F�����tN?꼆g첬�:g�B`��;�p5�k�§l>��gP-�6�ٗ�y���%�ؕ�֮-H���q���ޜ��㪡���i�O�I�kx_6)�f4*�,����{�Ks:��,�zW���ɥ^��q?�1�S�$+{ݵ�}�ٴ�y���c�R5M׿�0l/���X�m��bt�J72����J��Hʇ�xdwYu��'YU7㕮 Į�v�C.t��I�?� �ؤ����U�$��&yAhHHI�T��0�JA�¸gC �����wv��-���GO w98C ]�]۶ݬ��k�8���)/P -1052/R 4/StmF/StdCF/StrF/StdCF/U(`�xY`X���RN� )/V 4>> endobj 1097 0 obj <>/Metadata 27 0 R/Pages 1093 0 R/StructTreeRoot 43 0 R/Type/Catalog>> endobj 1098 0 obj <>/MediaBox[0 0 612 792]/Parent 1093 0 R/Resources<>/ProcSet[/PDF/Text/ImageC]/XObject<>>>/Rotate 0/StructParents 0/Tabs/S/Type/Page>> endobj 1099 0 obj <>stream Product Number: 0485 . �Q8�Ɖ���-�!�t�k�T��E�aA�%Q���,��j�� �%���&�>U��B�O'�h������R �x���ti���d���j���������n���� ���ae�i�:FM�Nq�8��p4t��GCC�u`1h�3�>� ba���*|L"��.�$� Manufacturer: Columbus Chemical Industries, Inc. N4335 Temkin Rd. All Rights Reserved. �&[�����ם�������Dae��-��m�1��Z��cey4���"^�N��� ����ʤ���,����C������v��v�>�� It is used as a food additive, for industrial cleaning and in a variety of industrial settings including: Although in weakened solutions it can be used as a food additive and in household cleaners, employees must treat ammonium hydroxide like any other hazardous chemical. ��I��w�럝�������۝zF ?�Ӝ���ř����"gAbe�]��^�:J9�j�xw������|����o��|:h"�n��OojP�f��'o6P�+�H/ v�?l�z�Q^�s�G�����vެ,���И՛E�=K����3@� 2186 0 obj <> endobj h�bbd``b`3��J ��H���$l@� �(�`o��(�(�*@�;Hh��b n�h�f`b����H.��g�� ��? Ammonium Hydroxide and Hazard Controls. Copyright © 2020 SafetySkills. Industrial ammonium hydroxide can be found in solutions of up to 30%. %%EOF Student Safety Sheets are teaching materials. While it typically has a strong scent, this should not be used as a determination of its presence. First Aid Procedures: Inhalation: Move to fresh air. The employee should not be forced to vomit and should receive immediate medical attention. It should also never be stored in areas with sewers. 1. 2204 0 obj <>/Filter/FlateDecode/ID[<6D1DC8DC60C0AB4991F6FC2528A8C5AA>]/Index[2186 33]/Info 2185 0 R/Length 91/Prev 202616/Root 2187 0 R/Size 2219/Type/XRef/W[1 2 1]>>stream It can be denoted by the symbols NH 3 (aq). %%EOF Columbus, WI. ©CLEAPSS 2019 Student safety sheets 37 Ammonium salts Substance Hazard Comment Ammonium chloride Solid and concentrated solution (if 1.8 M or more) HARMFUL. 0 The most effective hazard controls are elimination and substitution. contains about 5% sodium hydroxide, 1% potassium hydroxide, 0.2% silicon dioxide, 14 – 19% water and the remainder calcium hydroxide (it is used to absorb carbon dioxide). 0 Call 911 for immediate assistance if the employee requires artificial respiration. 1� �. endstream endobj startxref When working with ammonium hydroxide, PPE will generally include: For employees who are trained to clean spills or are working with high concentrations of ammonium hydroxide, additional PPE will likely be required. The most effective hazard controls are elimination and substitution. Student safety sheets 31 Sodium hydroxide also applies to Soda lime and Potassium hydroxide Substance Hazard Comment Sodium or potassium hydroxide Solid . 1125 0 obj <>stream … WARNING! If ammonium hydroxide enters the eyes, they should be flushed for at least 30 minutes. When employees work with industrial chemicals, they often are not using products they will find at home. If exposed, employees may experience: All these symptoms should be treated promptly and should be evaluated by a medical professional as soon as possible. Employers should also cover the hierarchy of hazard controls, ensuring all employees are familiar with effective forms of protection and how to use them. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 07/06/1998 Revision date: 11/21/2016 Supersedes: 12/29/2015 Version: 2.0 01/26/2018 EN (English US) Page 1 SECTION 1: Identification . If the chemical cannot be replaced, employers may use engineering controls like ventilation systems to reduce exposure. Ventilation rates should be matched to conditions. �Er��b`l R�̋%�\F� s�37 Although employees may use ammonium hydroxide both at home and at work, employers must ensure they are aware of the unique dangers of the chemical. 2218 0 obj <>stream Employers should use appropriate control measures for ammonium hydroxide, including enclosures that separate the employee from the process and ensuring the use of both local and general ventilation. PRODUCT AND COMPANY IDENTIFICATION. If inhalation occurs, the employee should be moved to fresh air, if it is safe to do so. Never store ammonium hydroxide at any solution with or near food or food-type products. W. ARNING: harmful if swallowed, causes serious eye irritation. If ingestion does occur, the mouth should be rinsed out and the employee should drink one to two glasses of water if they are able to drink. colorless liquid with a strong odor and bad taste, Four Steps to Conducting a Job Safety Analysis in the Canadian Workplace, Train over any hazardous chemicals that employees may be exposed to, Train employees to detect and respond to a, Provide training over exposure protection, including, Eye irritation, including redness and pain, Contact burns, including blisters and burns. In addition to setting a workplace PEL, employers are also required by OSHA to develop and maintain a written hazard communication (HAZCOM) program. Used in everything from household cleaners to industrial processes, it is toxic in all solutions. Product Use: Industrial, Manufacturing or Laboratory use . endstream endobj 2187 0 obj <>/Metadata 59 0 R/Outlines 74 0 R/PageLayout/OneColumn/Pages 2184 0 R/StructTreeRoot 189 0 R/Type/Catalog>> endobj 2188 0 obj <>/ExtGState<>/Font<>/XObject<>>>/Rotate 0/StructParents 0/Type/Page>> endobj 2189 0 obj <>stream It is corrosive to copper and zinc and can cause serious damage to skin and eyes. 1095 0 obj <> endobj �~0��>b��|т�JA|�*W� NTe`�df {���Vg`V� … h�bbd``b`ׁ�, ��$�":@�`�^�d-@� V�k��DH4�Xv@�g��$j��, ��!���� � ��K

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