The source is also providing more information like the publication year, authors and more. quantities obtained from such an anal. The results allowed good characterisation of both the ruling interactions and the medium structure. Take the time to validate and double check the source of the data. Finally, the Walden product showed significant dependence of the conductivity on the viscosity of the medium. Propylene carbonate. Solutions of tetraethylammonium tetrafluoroborate in propylene carbonate were studied by viscometry and densimetry over the This chapter provides viscosity of the binary liquid mixture of dimethyl carbonate and hexan-2-ol at various temperature and concentrations. dependences of the viscosity (η) of propylene carbonate (PC)/dimethoxyethane (DME) mixts. Among various semiempirical η(x)-functions available for data anal., only the R. McAllister (1960) equation fits the data precisely. Note: Cheméo is only indexing the data, follow the source links to retrieve the latest data. Acts as a solvent and viscosity reducer in coatings. remained constant over the temperature range studied. The conductivity-temperature relationship was found to have a better fitting on the Vogel-Tammann-Fulcher model than on the Arrhenius law. Join ResearchGate to find the people and research you need to help your work. Similar Compounds. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner. Predict properties. The thermodynamic and transport proprieties have been determined for the whole concentration range of N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (P14) and propylene carbonate (PC) binary mixtures in the temperature range 293.15–318.15 K. Strong effects of the mole fraction and temperature on these properties have been observed. In each case, the best-fit parameters, such as the pseudo activation energy, E a ∗ and ideal glass transition temperature, T0 are then extracted. This chapter provides viscosity of the binary liquid mixture of propylene carbonate and 1,4-dioxane at various temperature and concentrations. Propylene carbonate (PC) has also been used as a solvent/co-solvent to prepare electrolyte solutions for these energy storage devices. The concn. Thermodn. The solvation of tetraethylammonium carbonate were estimated using the approach suggested by Eyring and Andrade. Is particularly well suited for applications requiring a … Predict Chemical & Physical Properties of Et4NBF4 in propylene carbonate were estimated using the approach suggested by Eyring and Andrade. This chapter provides viscosity of the binary liquid mixture of dimethyl carbonate and propan-2-ol at various temperature and concentrations. was described by the Angell and Bachinskii equations. Generation of bulky cyclic carbonates such as octylene carbonate (OcC) and do-decylene carbonate (DoC) leads to an increase of the viscosity in the reaction mixture, yields are only 80 percent for OcC and 65 percent for DoC. The excess molar volumes VE, and viscosity deviations from the ideality, Δη, of each investigated mixture were then deduced from the experimental results, as well as, their apparent molar volumes, Vϕ, thermal expansion coefficients αp, and excess Gibbs free energies (ΔG∗E) of activation of viscous flow. In addition, the variation of conductivity with the molar fraction was well described by the Casteel-Amis equation. According to the Walden rule, the ionicity of each mixture was then evaluated as a function of the temperature from (283.15 to 353.15) K and of the composition. J. Phys. [on SciFinder(R)], Viscosity and Density of Solutions of Tetraethylammonium Tetrafluoroborate in Propylene Carbonate at Different Temperatures, The influence of temperature and concentration on viscous flow of solutions of Et 4 NBF 4 in propylene carbonate, Densities and viscosities of propylene carbonate with aromatic hydrocarbons (benzene, 1,4-dimethylbenzene and ethylbenzene) at 288.15, 298.15 and 308.15 K, Density, conductivity, viscosity, and excess properties of (pyrrolidinium nitrate-based Protic Ionic Liquid + propylene carbonate) binary mixture, Effect of Temperature and Composition on the Transport and Thermodynamic Properties of Binary Mixtures of Ionic Liquid N-Butyl-N-methylpyrrolidinium bis(Trifluoromethanesulfonyl)imide and Propylene Carbonate, Viscosity Behavior of Some Oxygen Containing Compounds, Viscosity of the binary liquid mixture of dimethyl carbonate and N,N-dimethylacetamide, Viscosity of the binary liquid mixture of dimethyl carbonate and hexan-2-ol, Viscosity of the binary liquid mixture of dimethyl carbonate and propan-2-ol. The thermodynamic parameters of activation of viscous flow of solutions remained constant over the temperature range studied. Solutions of tetraethylammonium tetrafluoroborate in propylene carbonate were studied by viscometry and densimetry over the The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). Download as Excel file EC number: 203-572-1 | CAS number: 108-32-7. The activation energy of viscous flow in solutions This chapter provides viscosity of propylene carbonate at various temperatures. | Find, read and cite all the research you need on ResearchGate ResearchGate has not been able to resolve any citations for this publication. The available value at 20°C is taken as the reference value. Particle size distribution (Granulometry), Solubility in organic solvents / fat solubility, Stability in organic solvents and identity of relevant degradation products, Storage stability and reactivity towards container material, Biodegradation in water and sediment: simulation tests, Additional information on environmental fate and behaviour, Short-term toxicity to aquatic invertebrates, Long-term toxicity to aquatic invertebrates, Toxicity to aquatic algae and cyanobacteria, Toxicity to aquatic plants other than algae, Endocrine disrupter testing in aquatic vertebrates – in vivo, Toxicity to soil macroorganisms except arthropods, Endocrine disrupter mammalian screening – in vivo (level 3), Direct observations: clinical cases, poisoning incidents and other, Exposure related observations in humans: other data, Additional physico-chemical properties of nanomaterials, Toxicokinetics, metabolism and distribution. This chapter provides viscosity of the binary liquid mixture of diethyl carbonate and pentan-1-ol at various temperature and concentrations. A 83 (2009) 2069. Densities (ρ) and viscosities (η) for the binary mixtures of propylene carbonate with tetrahydrofuran (THF), 1,4-dioxane, and acetylacetone were measured
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